Oxidation of aliphatic aldehydes by benzimidazolium fluorochromate in non aqueous medium – A kinetic and mechanistic study
نویسندگان
چکیده
منابع مشابه
Quinolinium Dichromate Oxidation of Aliphatic Aldehydes: A Kinetic Study
Kinetic data on the rates of quinolinium dichromate oxidation of a series of aliphatic aldehydes have been determined and discussed with reference to aldehyde hydration equilibria. Kinetic results support a pathway proceeding via a rate-determining oxidative decomposition of a chromate ester of an aldehyde hydrate. A cyclic transition state is suggested; being a Hückel-type system (4n + 2), thi...
متن کاملTripropylammonium Fluorochromate Oxidation of 2-Methyl-1-Propanol In Acid Medium: A Kinetic Study
1 P.G Dept. of Chemistry, Sir Sayyed College, Aurangabad, 431001, India. 2 Raje Shivaji College, Bajaj nagar, Waluj, Aurangabad, 431001, India. __________________________________________________________________________________________ Abstract: The Kinetics of oxidation of 2-methyl-1-propanol by tripropylammonium fluorochromate {TPAFC} has been studied Spectrophotometrically catalyzed by Sulphu...
متن کاملKinetic and Mechanistic Study of Oxidation of Piperazines by Bromamine-T in Acidic Medium
Oxidations of piperazine, 1-methylpiperazine and 1-ethylpiperazine by bromamine-T (BAT) in buffered acidic medium have been kinetically studied at 303 K. The reaction shows a first-order dependence of the rate each on [BAT]0 and [piperazine]0, and an inverse fractional-order dependence on [H]. The additions of halide ions and the reduction product of BAT, p-toluenesulfonamide, have no effect on...
متن کاملa corpus-based study of the frequency of personal pronouns in translated and comparable non-translated persian texts
چکیده ندارد.
15 صفحه اولOxidation of Some Aliphatic Aldehydes by Chloramine-t
Kinetic studies on the oxidation of acetaldehyde, propionaldehyde, nand tso-butyraldehyde have been made using diloramine-T as an oxidising agent in an alkaline medium. The reactions followed almost identical kinetics being first order with respect to both aldehyde and chloramine-T. The order with respect to alkali has been found to be almost equal to unity (0.8 to 0.90) . Effect of an increase...
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ژورنال
عنوان ژورنال: Arabian Journal of Chemistry
سال: 2017
ISSN: 1878-5352
DOI: 10.1016/j.arabjc.2013.07.043